A highly crystalline microporous hybrid organic–inorganic aluminosilicate resembling the AFI-type zeolite

Giuseppe Bellussi; Roberto Millini; Erica Montanari; Angela Carati; Caterina Rizzo; Wallace O. Parker; Giuseppe Cruciani; Alberto de Angelis; Lucia Bonoldi; Stefano Zanardi

doi:10.1039/C2CC33417H

A highly crystalline microporous hybrid organic–inorganic aluminosilicate resembling the AFI-type zeolite†

Giuseppe Bellussi,*^a Roberto Millini,^a Erica Montanari,^a Angela Carati,^a Caterina Rizzo,^a Wallace O. Parker, Jr.,^a Giuseppe Cruciani,^b Alberto de Angelis,^a Lucia Bonoldi^a and Stefano Zanardi^a

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^a Eni s.p.a., Refining & Marketing Division, San Donato Milanese Research Center, via F. Maritano 26, I-20097 San Donato Milanese, Italy
E-mail: giuseppe.bellussi@eni.com
Fax: +39-02-52036347
Tel: +39-02-52036555

^b Department of Physics and Earth Sciences, University of Ferrara, via G. Saragat 1, I-44100 Ferrara, Italy

Abstract

ECS-14, a crystalline microporous hybrid organic–inorganic aluminosilicate, has been synthesized by using 1,4-bis-(triethoxysilyl)-benzene (BTEB) as a source of silica. Its structure contains a system of linear channels with 12-membered ring openings, running along the [001] direction, resembling the pore architecture of the AFI framework type.

Chemical Communications

A highly crystalline microporous hybrid organic–inorganic aluminosilicate resembling the AFI-type zeolite†

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A highly crystalline microporous hybrid organic–inorganic aluminosilicate resembling the AFI-type zeolite

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