Issue 69, 2012
From the journal:

Chemical Communications

Solvent-induced intercluster rearrangements and the reversible luminescence responses in sulfide bridged gold(i)–silver(i) clusters†

Li-Qin Mo,a   Jian-Hua Jia,a   Li-jia Suna  and  Quan-Ming Wang*a  

* Corresponding authors

a State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, P. R. China
E-mail: qmwang@xmu.edu.cn
Fax: +86-592-2183047
Tel: +86-592-2184185

Abstract

Blue or yellow-green emission is observed from two different crystal types of the same gold(I)–silver(I) molecular cluster [SAu3Ag(L1)3](BF4)2 (L1 = 2-diphenylphosphino-4-methylpyridine) depending on the crystallization conditions; structural data suggest that intermolecular Au⋯Au interactions account for the luminescence vapochromic responses; a similar observation was made on two other pairs of analogues.

Graphical abstract: Solvent-induced intercluster rearrangements and the reversible luminescence responses in sulfide bridged gold(i)–silver(i) clusters

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Article information

DOI
https://doi.org/10.1039/C2CC33446A
Article type
Communication
Submitted
13 May 2012
Accepted
12 Jul 2012
First published
12 Jul 2012

Chem. Commun., 2012,48, 8691-8693

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Solvent-induced intercluster rearrangements and the reversible luminescence responses in sulfide bridged gold(I)–silver(I) clusters

L. Mo, J. Jia, L. Sun and Q. Wang, Chem. Commun., 2012, 48, 8691 DOI: 10.1039/C2CC33446A

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