Issue 66, 2012
From the journal:

Chemical Communications

Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels†

Javier Martí-Rujas,a   Luca Colombo,a   Jian Lü,b   Archan Dey,b   Giancarlo Terraneo,ab   Pierangelo Metrangolo,*ab   Tullio Pilatib  and  Giuseppe Resnati*ab  

* Corresponding authors

a Center for Nano Science and Technology@Polimi, Istituto Italiano di Tecnologia, Via Pascoli 70/3, 20133 Milano, Italy
E-mail: pierangelo.metrangolo@polimi.it, giuseppe.resnati@polimi.it

b NFMLab, Department of Chemistry, Materials, and Chemical Engineering, Politecnico di Milano, via Mancinelli 7, 20131 Milan, Italy

Abstract

Orthogonal self-assembly of an open organic framework showing 2D channels has been obtained by combining hydrogen and halogen bonding. The framework is able to host various guest molecules with a diverse set of steric demands and substitution patterns, and survives single-crystal-to-single-crystal guest exchanges from liquid and gas phases.

Graphical abstract: Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels

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Article information

DOI
https://doi.org/10.1039/C2CC33682K
Article type
Communication
Submitted
22 May 2012
Accepted
25 Jun 2012
First published
28 Jun 2012

Chem. Commun., 2012,48, 8207-8209

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Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels

J. Martí-Rujas, L. Colombo, J. Lü, A. Dey, G. Terraneo, P. Metrangolo, T. Pilati and G. Resnati, Chem. Commun., 2012, 48, 8207 DOI: 10.1039/C2CC33682K

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