Issue 70, 2012

[(CF3)4Au2(C5H5N)2] – a new alkyl gold(ii) derivative with a very short Au–Au bond

Abstract

A new gold(II) species [(CF3)4Au2(C5H5N)2] with a very short unsupported Au–Au bond (250.62(9) pm) was generated by photo irradiation of a silver aurate, [Ag(Py)2][Au(CF3)2], unambiguously characterized by 19F and 109Ag NMR studies.

Graphical abstract: [(CF3)4Au2(C5H5N)2] – a new alkyl gold(ii) derivative with a very short Au–Au bond

Supplementary files

Article information

Article type
Communication
Submitted
24 May 2012
Accepted
29 Jun 2012
First published
06 Jul 2012

Chem. Commun., 2012,48, 8805-8807

[(CF3)4Au2(C5H5N)2] – a new alkyl gold(II) derivative with a very short Au–Au bond

D. Zopes, C. Hegemann, W. Tyrra and S. Mathur, Chem. Commun., 2012, 48, 8805 DOI: 10.1039/C2CC33735E

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