A pillared metal–organic framework incorporated with 1,2,3-triazole moieties exhibiting remarkable enhancement of CO2 uptake

Wen-Yang Gao; Wuming Yan; Rong Cai; Kia Williams; Andrea Salas; Lukasz Wojtas; Xiaodong Shi; Shengqian Ma

doi:10.1039/C2CC34380K

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A pillared metal–organic framework incorporated with 1,2,3-triazole moieties exhibiting remarkable enhancement of CO₂ uptake†

Wen-Yang Gao,^a Wuming Yan,^b Rong Cai,^b Kia Williams,^a Andrea Salas,^a Lukasz Wojtas,^a Xiaodong Shi*^b and Shengqian Ma*^a

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* Corresponding authors

^a Department of Chemistry, University of South Florida, 4202 East Flower Avenue, Tampa, USA
E-mail: sqma@usf.edu
Fax: +1-813-974 3203
Tel: +1-813-974 5217

^b Department of Chemistry, West Virginia University, Morgantown, USA
E-mail: xiaodong.shi@mail.wvu.edu

Abstract

The replacement of the pillar ligand, 4,4′-bipyridine, in the prototypal pillared MOF, MOF-508, with the custom-designed ligand, 4,4′-(2H-1,2,3-triazole-2,4-diyl)dipyridine, affords a porous metal–triazolate framework, MTAF-3, which demonstrates remarkable enhancement of CO₂ uptake capacity by a factor of ∼3 compared to the parent MOF-508.

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Article information

DOI: https://doi.org/10.1039/C2CC34380K
Article type: Communication
Submitted: 19 Jun 2012
Accepted: 21 Jul 2012
First published: 23 Jul 2012

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Chem. Commun., 2012,48, 8898-8900

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A pillared metal–organic framework incorporated with 1,2,3-triazole moieties exhibiting remarkable enhancement of CO₂ uptake

W. Gao, W. Yan, R. Cai, K. Williams, A. Salas, L. Wojtas, X. Shi and S. Ma, Chem. Commun., 2012, 48, 8898 DOI: 10.1039/C2CC34380K

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