Issue 86, 2012
From the journal:

Chemical Communications

Crystal surface mediated structure transformation of a kinetic framework composed of multi-interactive ligand TPHAP and Co(ii)†

Yumi Yakiyama,a   Akira Ueda,b   Yasushi Morita*b  and  Masaki Kawano*a  

* Corresponding authors

a The Division of Advanced Materials Science, Pohang University of Science and Technology, (POSTECH), San-31, Hyoja-dong, Pohang 790-784, Namgu, South Korea
E-mail: mkawano@postech.ac.kr
Fax: +82 54 279 8736
Tel: +82 54 279 8740

b Department of Chemistry, Graduate School of Science, Osaka University, Machikaneyama 1-1, Osaka 560-0043, Toyonaka, Japan
E-mail: morita@chem.sci.osaka-u.ac.jp
Fax: +81 6 6850 5395
Tel: +81 6 6850 5393

Abstract

A tripyridyl multi-interactive ligand TPHAP is prepared by a one-pot reaction on a gram scale. Network formation of Co(II) with TPHAP− gave kinetic and thermally more stable products. The kinetic network showed an unprecedented dynamic network transformation on the crystal surface by a ligand exchange reaction.

Graphical abstract: Crystal surface mediated structure transformation of a kinetic framework composed of multi-interactive ligand TPHAP and Co(ii)

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Article information

DOI
https://doi.org/10.1039/C2CC35078E
Article type
Communication
Submitted
16 Jul 2012
Accepted
11 Sep 2012
First published
12 Sep 2012

Chem. Commun., 2012,48, 10651-10653

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Crystal surface mediated structure transformation of a kinetic framework composed of multi-interactive ligand TPHAP and Co(II)

Y. Yakiyama, A. Ueda, Y. Morita and M. Kawano, Chem. Commun., 2012, 48, 10651 DOI: 10.1039/C2CC35078E

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