Issue 79, 2012

Encapsulation of atmospheric CO2 by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges

Abstract

A decanuclear Cd complex has been found as a carbonate-containing capsule. The structure strongly resembles a ten-blade waterwheel with a central carbonate ligand surrounded by two superimposed Cd5O5 crowns with a pentagonal antiprism-like disposition. The capsule is doubly capped by two pentadentate perchlorate anions.

Graphical abstract: Encapsulation of atmospheric CO2 by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges

Supplementary files

Article information

Article type
Communication
Submitted
18 Jul 2012
Accepted
17 Aug 2012
First published
20 Aug 2012

Chem. Commun., 2012,48, 9915-9917

Encapsulation of atmospheric CO2 by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges

A. M. García-Deibe, C. Portela-García, M. Fondo, A. J. Mota and J. Sanmartín-Matalobos, Chem. Commun., 2012, 48, 9915 DOI: 10.1039/C2CC35171D

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