Issue 85, 2012

Mesoporous cross-linked polymer copolymerized with chiral BINAP ligand coordinated to a ruthenium species as an efficient heterogeneous catalyst for asymmetric hydrogenation

Abstract

We report here a successful preparation of a heterogeneous chiral catalyst from copolymerization of mesoporous cross-linked polymer with chiral BINAP ligands, followed by coordination of the BINAP with a ruthenium species, which exhibits high activity, excellent enantioselectivity, and extraordinary recyclability in asymmetric hydrogenation.

Graphical abstract: Mesoporous cross-linked polymer copolymerized with chiral BINAP ligand coordinated to a ruthenium species as an efficient heterogeneous catalyst for asymmetric hydrogenation

Supplementary files

Article information

Article type
Communication
Submitted
19 Jul 2012
Accepted
04 Sep 2012
First published
04 Sep 2012

Chem. Commun., 2012,48, 10505-10507

Mesoporous cross-linked polymer copolymerized with chiral BINAP ligand coordinated to a ruthenium species as an efficient heterogeneous catalyst for asymmetric hydrogenation

Q. Sun, X. Meng, X. Liu, X. Zhang, Y. Yang, Q. Yang and F. Xiao, Chem. Commun., 2012, 48, 10505 DOI: 10.1039/C2CC35192G

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