A series of goblet-like heterometallic pentanuclear [LnIIICuII4] clusters featuring ferromagnetic coupling and single-molecule magnet behavior

Qilong Zhu; Shengchang Xiang; Tianlu Sheng; Daqiang Yuan; Chaojun Shen; Chunhong Tan; Shengmin Hu; Xintao Wu

doi:10.1039/C2CC35935A

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A series of goblet-like heterometallic pentanuclear [Ln^IIICu^II₄] clusters featuring ferromagnetic coupling and single-molecule magnet behavior†

Qilong Zhu,^a Shengchang Xiang,^b Tianlu Sheng,^a Daqiang Yuan,^a Chaojun Shen,^a Chunhong Tan,^a Shengmin Hu^a and Xintao Wu*^a

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* Corresponding authors

^a State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: wxt@fjirsm.ac.cn
Fax: +86-591-83719238
Tel: +86-591-83719238

^b College of Chemistry and Materials, Fujian Normal University, Fuzhou, China

Abstract

A series of fascinating goblet-like clusters based on [Ln^IIICu^II₄] cores have been assembled from a flexible carboxylate ligand, which exhibit a dominant ferromagnetic exchange coupling and single-molecule magnet behavior.

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Article information

DOI: https://doi.org/10.1039/C2CC35935A
Article type: Communication
Submitted: 16 Aug 2012
Accepted: 11 Sep 2012
First published: 11 Sep 2012

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Chem. Commun., 2012,48, 10736-10738

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A series of goblet-like heterometallic pentanuclear [Ln^IIICu^II₄] clusters featuring ferromagnetic coupling and single-molecule magnet behavior

Q. Zhu, S. Xiang, T. Sheng, D. Yuan, C. Shen, C. Tan, S. Hu and X. Wu, Chem. Commun., 2012, 48, 10736 DOI: 10.1039/C2CC35935A

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