Issue 87, 2012
From the journal:

Chemical Communications

Synthesis of lithium corrole and its use as a reagent for the preparation of cyclopentadienyl zirconium and titanium corrole complexes†

Heather L. Buckley,a   Wayne A. Chomitz,a   Beata Koszarna,b   Mariusz Tasior,b   Daniel T. Gryko,bc   Penelope J. Brothersd  and  John Arnold*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, California, USA
E-mail: arnold@berkeley.edu
Fax: +1 510 643 5181
Tel: +1 510 643 5181

b Institute for Organic Chemistry, Polish Academy of Sciences, Warsaw, Poland
E-mail: dtgryko@icho.edu.pl
Tel: +48 22 3433063

c Warsaw University of Technology, Faculty of Chemistry, Warsaw, Poland

d School of Chemical Sciences, University of Auckland, Auckland, New Zealand
E-mail: p.brothers@auckland.ac.nz
Fax: +64 9 373 7422
Tel: +64 9 373 7599

Abstract

The lithium corrole complex (Mes2(p-OMePh)corrole)Li3·6THF (1·6THF), prepared via deprotonation of the free-base corrole with lithium amide, acts as precursor for the preparation of cyclopentadienyl zirconium(IV) corrole (2) and pentamethylcyclopentadienyl titanium(IV) corrole (3).

Graphical abstract: Synthesis of lithium corrole and its use as a reagent for the preparation of cyclopentadienyl zirconium and titanium corrole complexes

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Article information

DOI
https://doi.org/10.1039/C2CC35984G
Article type
Communication
Submitted
18 Aug 2012
Accepted
14 Sep 2012
First published
18 Sep 2012

Chem. Commun., 2012,48, 10766-10768

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Synthesis of lithium corrole and its use as a reagent for the preparation of cyclopentadienyl zirconium and titanium corrole complexes

H. L. Buckley, W. A. Chomitz, B. Koszarna, M. Tasior, D. T. Gryko, P. J. Brothers and J. Arnold, Chem. Commun., 2012, 48, 10766 DOI: 10.1039/C2CC35984G

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