Issue 100, 2012

γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes

Abstract

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90–95% ee).

Graphical abstract: γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes

Supplementary files

Article information

Article type
Communication
Submitted
26 Aug 2012
Accepted
31 Oct 2012
First published
01 Nov 2012

Chem. Commun., 2012,48, 12180-12182

γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes

S. M. Smith, G. L. Hoang, R. Pal, M. O. B. Khaled, L. S. W. Pelter, X. C. Zeng and J. M. Takacs, Chem. Commun., 2012, 48, 12180 DOI: 10.1039/C2CC36199J

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