Issue 96, 2012

Anomalous Staudinger reaction at intramolecular frustrated P–B Lewis pair frameworks

Abstract

The FLP-mesityl azide addition products 5, formed by FLP-addition to the terminal azide nitrogen atom, undergo N–N bond cleavage in an unusual variant of the Staudinger reaction upon thermolysis or photolysis to give an internally borane stabilized [P][double bond, length as m-dash]NH phosphinimine and a dimethylindazole derivative.

Graphical abstract: Anomalous Staudinger reaction at intramolecular frustrated P–B Lewis pair frameworks

Supplementary files

Article information

Article type
Communication
Submitted
18 Sep 2012
Accepted
15 Oct 2012
First published
31 Oct 2012

Chem. Commun., 2012,48, 11739-11741

Anomalous Staudinger reaction at intramolecular frustrated P–B Lewis pair frameworks

A. Stute, L. Heletta, R. Fröhlich, C. G. Daniliuc, G. Kehr and G. Erker, Chem. Commun., 2012, 48, 11739 DOI: 10.1039/C2CC36782C

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