Issue 100, 2012
From the journal:

Chemical Communications

Taming the germyliumylidene [CIGe:]+ and germathionium [CIGe[double bond, length as m-dash]S]+ ions by donor–acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene†

Yun Xiong,a   Shenglai Yao,a   Shigeyoshi Inoue,a   Andreas Berkefelda  and  Matthias Driess*a  

* Corresponding authors

a Technische Universität Berlin, Department of Chemistry, Metalorganics and Inorganic Materials, Sekr. C2, Strasse des 17. Juni 135, D-10623 Berlin, Germany
E-mail: matthias.driess@tu-berlin.de, http://www.driess.tu-berlin.de
Fax: +49 30-314-29732

Abstract

The novel chlorogermyliumylidene complex L[ClGe:]+ (L = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a ‘naked’ Cl− as a counter anion was synthesized through reaction of L with Cl2Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGe[double bond, length as m-dash]S]+ cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis.

Graphical abstract: Taming the germyliumylidene [CIGe:]+ and germathionium [CIGe [[double bond, length as m-dash]] S]+ ions by donor–acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene

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Article information

DOI
https://doi.org/10.1039/C2CC36926E
Article type
Communication
Submitted
24 Sep 2012
Accepted
31 Oct 2012
First published
02 Nov 2012

Chem. Commun., 2012,48, 12198-12200

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Taming the germyliumylidene [CIGe:]+ and germathionium [CIGe[double bond, length as m-dash]S]+ ions by donor–acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene

Y. Xiong, S. Yao, S. Inoue, A. Berkefeld and M. Driess, Chem. Commun., 2012, 48, 12198 DOI: 10.1039/C2CC36926E

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