Issue 96, 2012
From the journal:

Chemical Communications

Calcium amido-bisoxazoline complexes in asymmetric hydroamination/cyclisation catalysis†

Tracy D. Nixona  and  Benjamin D. Ward*a  

* Corresponding authors

a School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
E-mail: WardBD@Cardiff.ac.uk
Fax: +44 (0)29 208 74030
Tel: +44 (0)29 208 70302

Abstract

Calcium complexes bearing bis(oxazolinylphenyl)amine (BOPA) ligands have been prepared, and their redistribution chemistry studied. The complexes [Ca(R-BOPA){N(SiMe3)2}(THF)] (R = iPr 1a, Ph 1b and Bn 1c) are active in hydroamination catalysis and give the highest enantioselectivity reported for a calcium complex.

Graphical abstract: Calcium amido-bisoxazoline complexes in asymmetric hydroamination/cyclisation catalysis

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Article information

DOI
https://doi.org/10.1039/C2CC37021B
Article type
Communication
Submitted
27 Sep 2012
Accepted
23 Oct 2012
First published
23 Oct 2012
This article is Open Access
Creative Commons BY license

Chem. Commun., 2012,48, 11790-11792

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Calcium amido-bisoxazoline complexes in asymmetric hydroamination/cyclisation catalysis

T. D. Nixon and B. D. Ward, Chem. Commun., 2012, 48, 11790 DOI: 10.1039/C2CC37021B

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