Issue 13, 2013
From the journal:

Chemical Communications

Gold catalyzed stereoselective tandem hydroamination–formal aza-Diels–Alder reaction of propargylic amino esters†

Santos Fustero,*ab   Paula Bello,a   Javier Miró,a   María Sánchez-Roselló,ab   Miguel A. Maestro,c   Javier Gonzálezd  and  Carlos del Pozo*a  

* Corresponding authors

a Dept. de Química Orgánica, Universidad de Valencia, Burjassot, Spain
E-mail: santos.fustero@uv.es, carlos.pozo@uv.es

b Laboratorio de Moléculas Orgánicas, Centro de Investigación Príncipe Felipe, Valencia, Spain

c Dept. Química Fundamental, Universidad da Coruña, A Coruña, Spain

d Dept. Química Orgánica e Inorgánica, Universidad de Oviedo, Oviedo, Spain

Abstract

A gold-catalyzed tandem intramolecular hydroamination–formal aza-Diels–Alder reaction of propargylic amino esters is described. The overall process leads to the formation of a tetracyclic framework as a single diastereoisomer, with the creation of four bonds and five stereocenters.

Graphical abstract: Gold catalyzed stereoselective tandem hydroamination–formal aza-Diels–Alder reaction of propargylic amino esters

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC37796A
Article type
Communication
Submitted
27 Oct 2012
Accepted
21 Dec 2012
First published
03 Jan 2013

Chem. Commun., 2013,49, 1336-1338

Permissions

Request permissions

Gold catalyzed stereoselective tandem hydroamination–formal aza-Diels–Alder reaction of propargylic amino esters

S. Fustero, P. Bello, J. Miró, M. Sánchez-Roselló, M. A. Maestro, J. González and C. D. Pozo, Chem. Commun., 2013, 49, 1336 DOI: 10.1039/C2CC37796A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements