Oxidation of cycloalkanes by H2O2 using a copper–hemicryptophane complex as a catalyst

Olivier Perraud; Alexander B. Sorokin; Jean-Pierre Dutasta; Alexandre Martinez

doi:10.1039/C2CC37829A

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Oxidation of cycloalkanes by H₂O₂ using a copper–hemicryptophane complex as a catalyst†

Olivier Perraud,^a Alexander B. Sorokin,^b Jean-Pierre Dutasta*^a and Alexandre Martinez*^a

Author affiliations

* Corresponding authors

^a Laboratoire de Chimie, CNRS, Université Lyon 1, École Normale Supérieure de Lyon, 46 Allée d'Italie, F-69364 Lyon, France
E-mail: alexandre.martinez@ens-lyon.fr
Fax: +33 4 7272 8860
Tel: +33 4 7272 8863

^b IRCELYON, UMR 5256, CNRS – Université Lyon 1, 2 av. A. Einstein, F-69626 Villeurbanne, France
E-mail: alexander.sorokin@ircelyon.univ-lyon1.fr
Tel: +33 4 7244 5337

Abstract

Efficient alkane C–H bond oxidation was achieved using a newly designed Cu(II)–hemicryptophane complex. Protection of the copper site in the inner cavity of the host leads to enhanced yields and allows discriminating cyclohexane from cyclooctane or adamantane in competitive experiments.

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Article information

DOI: https://doi.org/10.1039/C2CC37829A
Article type: Communication
Submitted: 20 Jul 2012
Accepted: 21 Dec 2012
First published: 02 Jan 2013

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Chem. Commun., 2013,49, 1288-1290

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Oxidation of cycloalkanes by H₂O₂ using a copper–hemicryptophane complex as a catalyst

O. Perraud, A. B. Sorokin, J. Dutasta and A. Martinez, Chem. Commun., 2013, 49, 1288 DOI: 10.1039/C2CC37829A

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