Issue 5, 2012
From the journal:

CrystEngComm

Three unprecedented open frameworks based on a pyridyl-carboxylate: synthesis, structures and properties†

Shengqun Su,ab   Wan Chen,ab   Xuezhi Song,ab   Min Zhu,a   Chao Qin,a   Shuyan Song,a   Zhiyong Guo,d   Song Wang,ab   Zhaoming Hao,ab   Guanghua Lic  and  Hongjie Zhang*a  

* Corresponding authors

a State Key Laboratory of Rare Earth Resource Utilizations, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, P. R. China
E-mail: hongjie@ciac.jl.cn
Fax: +86 431 85698041
Tel: +86 431 85262127

b Graduate School of the Chinese Academy of Sciences, Beijing, P. R. China

c State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, P. R. China

d Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas, USA

Abstract

Three open frameworks, [Ni(pnta)2]·1.3DMF (1), [Zn2(pnta)3(OH)]·2DMF (2), and [Cd(pnta)2]·3.8DMF (3), were obtained by solvothermal reactions between 6-(pyridin-4-yl)nicotinic acid (Hpnta) and nickel(II), zinc(II) and cadmium(II) nitrate, respectively. Compound 1 is a chiral framework with a fourfold interpenetrated diamondoid network structure and two types of chiral channels. Compound 2 also possesses the fourfold interpenetrated adamantanoid architecture with helical rhombic nanotube-like channels, each of which has two sides of double-layer walls and two other sides of single-layer walls. Compound 3 is a rarely reported double-walled framework with bcu topology. The luminescent properties of compounds 2 and 3 have been studied in the solid state at room temperature.

Graphical abstract: Three unprecedented open frameworks based on a pyridyl-carboxylate: synthesis, structures and properties

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Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CE05948G
Article type
Paper
Submitted
26 Jul 2011
Accepted
07 Dec 2011
First published
20 Dec 2011

CrystEngComm, 2012,14, 1681-1686

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Three unprecedented open frameworks based on a pyridyl-carboxylate: synthesis, structures and properties

S. Su, W. Chen, X. Song, M. Zhu, C. Qin, S. Song, Z. Guo, S. Wang, Z. Hao, G. Li and H. Zhang, CrystEngComm, 2012, 14, 1681 DOI: 10.1039/C2CE05948G

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