On the origin of the electroactive poly(vinylidene fluoride) β-phase nucleation by ferrite nanoparticlesvia surface electrostatic interactions

Abstract

Flexible multiferroic 0–3 composite films, comprising NiFe₂O₄ and CoFe₂O₄ ferrite nanoparticles in a polyvinylidene fluoride (PVDF) matrix, have been prepared by solvent casting and melt crystallization to investigate the polymer β-phase nucleation mechanism. Infrared spectroscopy confirms the nucleation of the polymeric electroactive β-phase with the addition of both ferrites, although the loading of ferrite nanoparticles needed to obtain the highest amount of β-phase was found to be one order of magnitude higher in the NiFe₂O₄/PVDF nanocomposites. Transmission electron microscopy imaging and thermogravimetric analyses indicate the formation of an interface in the nanocomposites with the β-phase nucleation. It is shown that the essential factor for the nucleation of the β-phase in the ferrites/PVDF nanocomposites is the static electric interaction between the magnetic particles with a negative zeta potential and the CH₂ groups having a positive charge density.