Hydrogen bonded chiral sheet self-assembled from a C3-symmetric tricarbamate

Rajiv K. Singh; Xiaodong Hou; Molly Overby; Matthew Schober; Qianli Chu

doi:10.1039/C2CE25487E

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Hydrogen bonded chiral sheet self-assembled from a C₃-symmetric tricarbamate†

Rajiv K. Singh,^a Xiaodong Hou,^a Molly Overby,^a Matthew Schober^a and Qianli Chu*^a

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* Corresponding authors

^a Department of Chemistry, University of North Dakota, Grand Forks, ND 58202, USA
E-mail: chu@chem.und.edu
Fax: +1-701-777-2331
Tel: +1-701-777-3941

Abstract

A crystalline chiral sheet spontaneously assembled under mild conditions from benzene-1,3,5-triyl tris(propylcarbamate), which is a C₃-symmetric supramolecular atropisomer. The sheet-like structure was directly observed by TEM, and confirmed by powder and single crystal X-ray diffraction analysis.

This article is part of the themed collection: New Talent: Americas

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Article information

DOI: https://doi.org/10.1039/C2CE25487E
Article type: Communication
Submitted: 03 Apr 2012
Accepted: 31 May 2012
First published: 11 Jul 2012

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CrystEngComm, 2012,14, 6132-6135

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Hydrogen bonded chiral sheet self-assembled from a C₃-symmetric tricarbamate

R. K. Singh, X. Hou, M. Overby, M. Schober and Q. Chu, CrystEngComm, 2012, 14, 6132 DOI: 10.1039/C2CE25487E

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