Issue 8, 2013
From the journal:

CrystEngComm

Solvent diffusion and binding in a ‘nonporous’ molecular crystal†

Tia Jacobsa  and  Leonard J. Barbour*a  

* Corresponding authors

a Department of Chemistry and Polymer Science, University of Stellenbosch, Matieland, 7602, South Africa
E-mail: ljb@sun.ac.za
Fax: +27 (0) 21 808 3849
Tel: +27 (0) 21 808 3335

Abstract

Crystals of a series of solvated cadmium-based metallocycles undergo single-crystal to single-crystal transformations (SCTSCT) upon desolvation to yield an empty apohost; these transiently porous crystals then allow the diffusion of bulky solvent molecules.

Graphical abstract: Solvent diffusion and binding in a ‘nonporous’ molecular crystal

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Article information

DOI
https://doi.org/10.1039/C2CE26404H
Article type
Communication
Submitted
30 Aug 2012
Accepted
08 Oct 2012
First published
29 Oct 2012

CrystEngComm, 2013,15, 1512-1514

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Solvent diffusion and binding in a ‘nonporous’ molecular crystal

T. Jacobs and L. J. Barbour, CrystEngComm, 2013, 15, 1512 DOI: 10.1039/C2CE26404H

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