Issue 3, 2013
From the journal:

CrystEngComm

Novel heptanuclear copper(i) iodide cluster with a pinwheel shape†

Sanghun Cheon,a   Tae Ho Kim,a   Youngeun Jeon,a   Jineun Kim*a  and  Ki-Min Park*a  

* Corresponding authors

a Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 660-701, S. Korea
E-mail: jekim@gnu.ac.kr, kmpark@gnu.ac.kr

Abstract

From the reaction of CuI with an N,S-donor ligand (L) under different molar ratios, two discrete polynuclear copper(I) iodide complexes, [Cu2I2L2] (1) and [Cu7I7L3] (2) were isolated and characterised. Complex 1 contains a rhomboid-type Cu2I2 cluster, whilst complex 2 is the first example showing a pinwheel-type Cu7I7 cluster.

Graphical abstract: Novel heptanuclear copper(i) iodide cluster with a pinwheel shape

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Article information

DOI
https://doi.org/10.1039/C2CE26664D
Article type
Communication
Submitted
11 Oct 2012
Accepted
05 Nov 2012
First published
06 Nov 2012

CrystEngComm, 2013,15, 451-454

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Novel heptanuclear copper(I) iodide cluster with a pinwheel shape

S. Cheon, T. H. Kim, Y. Jeon, J. Kim and K. Park, CrystEngComm, 2013, 15, 451 DOI: 10.1039/C2CE26664D

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