Issue 2, 2013

Propargyl Claisen rearrangement: allene synthesis and beyond

Abstract

The propargyl Claisen rearrangement is a known protocol to gain access to functionalized allenes through the [3,3]-sigmatropic transformation of propargyl vinyl ethers. The correct use of appropriate propargyl vinyl ethers as starting materials coupled with suitable reaction conditions can aid in the development of new domino methodologies in which the allenes are valuable intermediates in route to a wide range of important classes of organic compounds.

Graphical abstract: Propargyl Claisen rearrangement: allene synthesis and beyond

Article information

Article type
Tutorial Review
Submitted
02 Aug 2012
First published
04 Oct 2012

Chem. Soc. Rev., 2013,42, 458-471

Propargyl Claisen rearrangement: allene synthesis and beyond

D. Tejedor, G. Méndez-Abt, L. Cotos and F. García-Tellado, Chem. Soc. Rev., 2013, 42, 458 DOI: 10.1039/C2CS35311C

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