Issue 11, 2012

Challenges in the catalytic synthesis of cyclic and polymeric carbonates from epoxides and CO2

Abstract

The addition of carbon dioxide to epoxides to produce either cyclic carbonates or polycarbonates is an important reaction allowing the conversion of a renewable, inexpensive and non-toxic feedstock such as CO2 into useful products with many potential applications. In this perspective article, an overview of the type of catalysts used for this reaction, the mechanisms with which they operate and the parameters influencing their activity and selectivity are presented and discussed critically. In this context, the main challenges to be tackled in this vibrant area of research are highlighted.

Graphical abstract: Challenges in the catalytic synthesis of cyclic and polymeric carbonates from epoxides and CO2

Article information

Article type
Perspective
Submitted
30 May 2012
Accepted
26 Jun 2012
First published
29 Jun 2012

Catal. Sci. Technol., 2012,2, 2169-2187

Challenges in the catalytic synthesis of cyclic and polymeric carbonates from epoxides and CO2

P. P. Pescarmona and M. Taherimehr, Catal. Sci. Technol., 2012, 2, 2169 DOI: 10.1039/C2CY20365K

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