Issue 12, 2012
From the journal:

Dalton Transactions

Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone†

Charles Romain,a   Vitor Rosa,ab   Christophe Fliedel,ab   Frédéric Bier,a   Frédéric Hild,a   Richard Welter,a   Samuel Dagorne*a  and  Teresa Avilés*b  

* Corresponding authors

a Laboratoire DECOMET, Institut de Chimie de Strasbourg, CNRS-Université de Strasbourg, 1 rue Blaise Pascal, 67000 Strasbourg, France
E-mail: dagorne@unistra.fr

b REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Portugal
E-mail: tap@dq.fct.unl.pt
Fax: +351 212 948 550

Abstract

Zinc alkyl cations supported by N,N-BIAN-type bidentate ligands were found to be highly active in the immortal ROP of ε-caprolactone to yield narrowly disperse and chain length-controlled poly(ε-caprolactone), whether in solution or bulk polymerization conditions.

Graphical abstract: Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone

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Article information

DOI
https://doi.org/10.1039/C2DT12336C
Article type
Communication
Submitted
03 Dec 2011
Accepted
24 Jan 2012
First published
10 Feb 2012

Dalton Trans., 2012,41, 3377-3379

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Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone

C. Romain, V. Rosa, C. Fliedel, F. Bier, F. Hild, R. Welter, S. Dagorne and T. Avilés, Dalton Trans., 2012, 41, 3377 DOI: 10.1039/C2DT12336C

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