Issue 15, 2012

Deprotonation of C-alkyl groups of cationic N-heterocyclic ligands

Abstract

The C-alkyl groups of C-alkylpyrazinium-derived ligands have been selectively deprotonated by K[N(SiMe3)2], through charge-controlled processes, to give neutral products that contain C-alkylidenepyrazine-derived ligands.

Graphical abstract: Deprotonation of C-alkyl groups of cationic N-heterocyclic ligands

Supplementary files

Article information

Article type
Communication
Submitted
19 Dec 2011
Accepted
09 Feb 2012
First published
09 Feb 2012

Dalton Trans., 2012,41, 4313-4315

Deprotonation of C-alkyl groups of cationic N-heterocyclic ligands

J. A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and V. Pruneda, Dalton Trans., 2012, 41, 4313 DOI: 10.1039/C2DT30246B

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