Issue 33, 2012

Synthesis of diamondoid lanthanide–polyoxometalate solids as tunable photoluminescent materials

Abstract

The reaction between polyoxometalate (POM) [TBA]12[WZn{Zn(H2O)}2(ZnW9O34)2] (TBA = tetrabutyl ammonium) and lanthanide (Ln) nitrate (Ln = La, Eu and Tb) in a mixed solvent of CH3CN and DMF yielded three noncentrosymmetric diamondoid Ln–POM solid materials, {[Ln2(DMF)8(H2O)6][ZnW12O40]}·4DMF (Ln–POM; Ln = La, Eu and Tb). In these compounds, the {ZnW12O40} unit, transferred from the metastable [WZn{Zn(H2O)}2(ZnW9O34)2] cluster, acts as a tetradentate ligand to connect with four Ln nodes, while the Ln ion links up two {ZnW12O40} units. These compounds generated interesting luminescence emissions that are dependent on the Ln ions and their ratios. White light emission was obtained by a doped approach with a rational ratio of the Eu3+ and Tb3+ ions.

Graphical abstract: Synthesis of diamondoid lanthanide–polyoxometalate solids as tunable photoluminescent materials

Supplementary files

Article information

Article type
Paper
Submitted
28 Feb 2012
Accepted
29 May 2012
First published
30 May 2012

Dalton Trans., 2012,41, 10091-10096

Synthesis of diamondoid lanthanide–polyoxometalate solids as tunable photoluminescent materials

W. Zhao, C. Zou, L. Shi, J. Yu, G. Qian and C. Wu, Dalton Trans., 2012, 41, 10091 DOI: 10.1039/C2DT30481C

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