Issue 30, 2012
From the journal:

Dalton Transactions

Cooperation between metal and ligand in oxygen atom transport by N-confused porphyrin oxorhenium(v) complexes†

Takaaki Yamamoto,a   Motoki Toganoha  and  Hiroyuki Furuta*ab  

* Corresponding authors

a Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395, Japan
E-mail: hfuruta@cstf.kyushu-u.ac.jp
Fax: (+81)92-802-2865

b International Research Center for Molecular Systems, Kyushu University, Fukuoka 819-0395, Japan

Abstract

N-Confused porphyrin oxorhenium(V) complexes were prepared and their X-ray structures were elucidated. The oxorhenium(V) complexes can transfer oxygen atom from pyridine N-oxide to triphenylphosphine, in which unique cooperation between metal and ligand was observed.

Graphical abstract: Cooperation between metal and ligand in oxygen atom transport by N-confused porphyrin oxorhenium(v) complexes

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Article information

DOI
https://doi.org/10.1039/C2DT30885A
Article type
Communication
Submitted
24 Apr 2012
Accepted
25 May 2012
First published
28 May 2012

Dalton Trans., 2012,41, 9154-9157

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Cooperation between metal and ligand in oxygen atom transport by N-confused porphyrin oxorhenium(V) complexes

T. Yamamoto, M. Toganoh and H. Furuta, Dalton Trans., 2012, 41, 9154 DOI: 10.1039/C2DT30885A

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