Issue 38, 2012
From the journal:

Dalton Transactions

Stable, trinuclear Zn(ii)- and Cd(ii)-metallocycles: TWIM-MS, photophysical properties, and nanofiber formation†

Anthony Schultz,a   Yan Cao,b   Mingjun Huang,b   Stephen Z. D. Cheng,b   Xiaopeng Li,a   Charles N. Moorefield,c   Chrys Wesdemiotis*ab  and  George R. Newkome*abc  

* Corresponding authors

a Department of Chemistry, The University of Akron, Akron, OH 44325-4717, USA

b Department of Polymer Science, The University of Akron, Akron, OH 44325-4717, USA

c The Maurice Morton Institute for Polymer Science, The University of Akron, Akron, OH 44325-4717, USA
E-mail: newkome@uakron.edu, wesdemiotis@uakron.edu
Fax: +1 330-972-2368
Tel: +1 330-972-8595

Abstract

A series of trimeric, Zn(II)- and Cd(II)-metallocycles is reported. Structural characterization of the highly stable triangles was supported by traveling-wave ion mobility-mass spectrometry (TWIM-MS) and gradient tandem mass spectrometry (gMS2). Their unique photophysical properties and self-assembly to form nanofibers are also described.

Graphical abstract: Stable, trinuclear Zn(ii)- and Cd(ii)-metallocycles: TWIM-MS, photophysical properties, and nanofiber formation

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Article information

DOI
https://doi.org/10.1039/C2DT31813J
Article type
Communication
Submitted
18 Apr 2012
Accepted
16 Aug 2012
First published
20 Aug 2012

Dalton Trans., 2012,41, 11573-11575

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Stable, trinuclear Zn(II)- and Cd(II)-metallocycles: TWIM-MS, photophysical properties, and nanofiber formation

A. Schultz, Y. Cao, M. Huang, S. Z. D. Cheng, X. Li, C. N. Moorefield, C. Wesdemiotis and G. R. Newkome, Dalton Trans., 2012, 41, 11573 DOI: 10.1039/C2DT31813J

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