Issue 3, 2013

Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

Abstract

Four platinum(II) complexes bearing a boron-based PBP pincer ligand and chloride, hydride, triflate, and bis(trifluoromethanesulfonyl)imide were synthesized and structurally characterized. PBP-platinum chloride was proven to be an active catalyst for the hydrosilylation reaction using 1-decene and triethylsilane.

Graphical abstract: Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
17 Aug 2012
Accepted
01 Nov 2012
First published
20 Nov 2012

Dalton Trans., 2013,42, 625-629

Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

H. Ogawa and M. Yamashita, Dalton Trans., 2013, 42, 625 DOI: 10.1039/C2DT31892J

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