Issue 3, 2013

TICT fluorescence of N-borylated 2,5-diarylpyrroles: a gear like dual motion in the excited state

Abstract

A significantly red-shifted fluorescence and a high fluorescence quantum yield for the emission from the twisted intramolecular charge transfer (TICT) state are attained in new aminoboranes, N-borylated 2,5-diarylpyrroles. A gear like dual structural motion in the excited state is responsible for their large Stokes shifts.

Graphical abstract: TICT fluorescence of N-borylated 2,5-diarylpyrroles: a gear like dual motion in the excited state

Supplementary files

Article information

Article type
Communication
Submitted
15 Sep 2012
Accepted
08 Oct 2012
First published
09 Oct 2012

Dalton Trans., 2013,42, 620-624

TICT fluorescence of N-borylated 2,5-diarylpyrroles: a gear like dual motion in the excited state

T. Taniguchi, J. Wang, S. Irle and S. Yamaguchi, Dalton Trans., 2013, 42, 620 DOI: 10.1039/C2DT32134C

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