Issue 4, 2013
From the journal:

Dalton Transactions

A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides†

Andrew J. Roering,‡a   L. Taylor Elrod,§a   Justin K. Pagano,a   Sarah L. Guillot,a   Stephanie M. Chan,a   Joseph M. Tanskib  and  Rory Waterman*a  

* Corresponding authors

a Department of Chemistry, University of Vermont, Cook Physical Sciences Building, Burlington, VT 05405, USA
E-mail: rory.waterman@uvm.edu
Fax: +1 802 656-8705
Tel: +1 802 656-0278

b Department of Chemistry, Vassar College, Poughkeepsie, NY, USA

Abstract

A general, atom-economical method for the synthesis of phosphaalkenes is reported via the net coupling of primary alkyl or aryl phosphines with aryl or alkyl isocyanides at zirconium. The phosphorus-containing ligand can be liberated as the phosphaformamide from zirconium by reaction with an organic electrophile.

Graphical abstract: A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides

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Article information

DOI
https://doi.org/10.1039/C2DT32322B
Article type
Paper
Submitted
02 Oct 2012
Accepted
18 Oct 2012
First published
22 Oct 2012

Dalton Trans., 2013,42, 1159-1167

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A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides

A. J. Roering, L. T. Elrod, J. K. Pagano, S. L. Guillot, S. M. Chan, J. M. Tanski and R. Waterman, Dalton Trans., 2013, 42, 1159 DOI: 10.1039/C2DT32322B

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