Issue 44, 2012

Benzoxazole and benzimidazole heterocycle-grafted graphene for high-performance supercapacitor electrodes

Abstract

An efficient method for the preparation of benzoxazole and benzimidazole covalently grafted graphene and their application as high performance electrode materials for supercapacitors is reported. The synthesis of such covalently functionalized graphene materials first involves a cyclization reaction of carboxylic groups on graphene oxide with the hydroxyl and aminos groups on o-aminophenol and o-phenylenediamine, and subsequent reduction by hydrazine. Results of Fourier transformed infrared spectroscopy (FT-IR), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and thermogravimetric analysis (TGA) have confirmed that the covalent functionalization of graphene is achieved through the formation of benzoxazole and benzimidazole on the graphene sheets. The functionalized graphene materials are revealed to consist of corrugation and scrolling morphologies with less aggregation, indicating the effectiveness of functionalization in preventing restacking/aggregation of the graphene sheets. Furthermore, when applied as supercapacitor electrodes, the functionalized graphene materials exhibit good electrochemical performances in terms of high specific capacitance (730 and 781 F gāˆ’1 for benzoxazole and benzimidazole grafted graphene, respectively, at a current density of 0.1 A gāˆ’1) and good cycling stability, implying their potential for energy storage applications.

Graphical abstract: Benzoxazole and benzimidazole heterocycle-grafted graphene for high-performance supercapacitor electrodes

Supplementary files

Article information

Article type
Paper
Submitted
06 Aug 2012
Accepted
14 Sep 2012
First published
08 Oct 2012

J. Mater. Chem., 2012,22, 23439-23446

Benzoxazole and benzimidazole heterocycle-grafted graphene for high-performance supercapacitor electrodes

W. Ai, W. Zhou, Z. Du, Y. Du, H. Zhang, X. Jia, L. Xie, M. Yi, T. Yu and W. Huang, J. Mater. Chem., 2012, 22, 23439 DOI: 10.1039/C2JM35234F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements