Issue 40, 2012
From the journal:

Journal of Materials Chemistry

Transition metal-catalyzed C–H activation as a route to structurally diverse di(arylthiophenyl)-diketopyrrolopyrroles†

Junxiang Zhang,a   Dun-Yen Kang,a   Stephen Barlowa  and  Seth R. Marder*a  

* Corresponding authors

a School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics, Georgia Institute of Technology, Atlanta, GA 30332-0400, USA
E-mail: seth.marder@chemistry.gatech.edu

Abstract

Dithiophenyldiketopyrrolopyrroles can be directly (hetero)arylated in moderate to excellent yields by Pd-catalyzed coupling to the CH position of a fluoro(hetero)arene (in the presence of Ag2CO3) or the CBr position of a bromo(hetero)arene.

Graphical abstract: Transition metal-catalyzed C–H activation as a route to structurally diverse di(arylthiophenyl)-diketopyrrolopyrroles

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Article information

DOI
https://doi.org/10.1039/C2JM35398A
Article type
Communication
Submitted
10 Aug 2012
Accepted
03 Sep 2012
First published
14 Sep 2012

J. Mater. Chem., 2012,22, 21392-21394

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Transition metal-catalyzed C–H activation as a route to structurally diverse di(arylthiophenyl)-diketopyrrolopyrroles

J. Zhang, D. Kang, S. Barlow and S. R. Marder, J. Mater. Chem., 2012, 22, 21392 DOI: 10.1039/C2JM35398A

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