Issue 5, 2012

A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

Abstract

A NiII complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.

Graphical abstract: A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

Supplementary files

Article information

Article type
Letter
Submitted
25 Oct 2011
Accepted
29 Feb 2012
First published
19 Mar 2012

New J. Chem., 2012,36, 1149-1152

A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

O. R. Luca, S. J. Konezny, J. D. Blakemore, D. M. Colosi, S. Saha, G. W. Brudvig, V. S. Batista and R. H. Crabtree, New J. Chem., 2012, 36, 1149 DOI: 10.1039/C2NJ20912H

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