Issue 3, 2012

Thiophene-substituted aza-bodipy as a strategic synthon for the design of near-infrared dyes

Abstract

Original aza-bodipy dyes functionalised by thiophene moieties in 3,5 or 1,7 positions were prepared and characterised by X-ray crystallography. The 3,5 substituted compound 3 exhibits promising photophysical properties red-shifted in the NIR spectral range. Furthermore, the presence of bromide atoms has allowed π-conjugated skeleton extension via Sonogashira cross-coupling.

Graphical abstract: Thiophene-substituted aza-bodipy as a strategic synthon for the design of near-infrared dyes

Supplementary files

Article information

Article type
Paper
Submitted
07 Nov 2011
Accepted
13 Dec 2011
First published
09 Jan 2012

New J. Chem., 2012,36, 768-773

Thiophene-substituted aza-bodipy as a strategic synthon for the design of near-infrared dyes

Q. Bellier, F. Dalier, E. Jeanneau, O. Maury and C. Andraud, New J. Chem., 2012, 36, 768 DOI: 10.1039/C2NJ20943H

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