Issue 26, 2012
From the journal:

Organic & Biomolecular Chemistry

Metallic organophosphates as catalysts in asymmetric synthesis: a return journey†

Alejandro Parra,*a   Silvia Reboredo,b   Ana M. Martín Castroa  and  José Alemán*a  

* Corresponding authors

a Departamento de Química Orgánica (Módulo 01), Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049-Madrid, Spain
E-mail: jose.aleman@uam.es, alejandro.parra@uam.es

b Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Spain

Abstract

This perspective article provides a general overview of the most relevant topics in the applications of chiral metallic organophosphates. A brief introduction along with a historic comparative profile of the BINOL and phosphoric acid analogues are given. Next, a selection of the most outstanding uses of the catalysts according to the employed metal is presented.

Graphical abstract: Metallic organophosphates as catalysts in asymmetric synthesis: a return journey

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Article information

DOI
https://doi.org/10.1039/C2OB25479D
Article type
Perspective
Submitted
05 Mar 2012
Accepted
13 Apr 2012
First published
16 Apr 2012

Org. Biomol. Chem., 2012,10, 5001-5020

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Metallic organophosphates as catalysts in asymmetric synthesis: a return journey

A. Parra, S. Reboredo, A. M. Martín Castro and J. Alemán, Org. Biomol. Chem., 2012, 10, 5001 DOI: 10.1039/C2OB25479D

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