Issue 10, 2012
From the journal:

Polymer Chemistry

Through-space conjugated polymers consisting of planar chiral pseudo-ortho-linked [2.2]paracyclophane†

Yasuhiro Morisaki,*a   Ryoyu Hifumi,a   Lin Lin,a   Kenichi Inoshitaa  and  Yoshiki Chujo*a  

* Corresponding authors

a Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: ymo@chujo.synchem.kyoto-u.ac.jp, chujo@chujo.synchem.kyoto-u.ac.jp

Abstract

Herein, we describe the synthesis and chiroptical properties of through-space conjugated polymers with enantiopure planar chiral (R)- and (S)-pseudo-ortho-disubstituted [2.2]paracyclophane skeletons. The polymers exhibited intense circularly polarized luminescence in dilute solutions due to their conformationally stable planar chiral zigzag structures.

Graphical abstract: Through-space conjugated polymers consisting of planar chiral pseudo-ortho-linked [2.2]paracyclophane

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Article information

DOI
https://doi.org/10.1039/C2PY20530K
Article type
Communication
Submitted
17 Jul 2012
Accepted
31 Jul 2012
First published
13 Aug 2012

Polym. Chem., 2012,3, 2727-2730

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Through-space conjugated polymers consisting of planar chiral pseudo-ortho-linked [2.2]paracyclophane

Y. Morisaki, R. Hifumi, L. Lin, K. Inoshita and Y. Chujo, Polym. Chem., 2012, 3, 2727 DOI: 10.1039/C2PY20530K

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