Issue 28, 2012
From the journal:

RSC Advances

The Au(iii)-catalyzed coupling reactions between alcohols and N-heterocycles via C–H bond activation†

Honglai Jiang,a   Jin Xie,a   Aijun Lin,a   Yixiang Chenga  and  Chengjian Zhu*ab  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China
E-mail: cjzhu@nju.edu.cn

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, P. R. China

Abstract

A novel and highly efficient dehydrogenative C–C coupling between sp3 C–H and sp2 C–H bonds catalyzed by gold has been developed using environmentally benign tert-butyl hydroperoxide as oxidant. This new methodology provides a facile access to acylate N-heterocycles.

Graphical abstract: The Au(iii)-catalyzed coupling reactions between alcohols and N-heterocycles via C–H bond activation

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Article information

DOI
https://doi.org/10.1039/C2RA22120A
Article type
Communication
Submitted
11 Sep 2012
Accepted
14 Sep 2012
First published
17 Sep 2012

RSC Adv., 2012,2, 10496-10498

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The Au(III)-catalyzed coupling reactions between alcohols and N-heterocycles via C–H bond activation

H. Jiang, J. Xie, A. Lin, Y. Cheng and C. Zhu, RSC Adv., 2012, 2, 10496 DOI: 10.1039/C2RA22120A

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