Issue 33, 2012
From the journal:

RSC Advances

Ti(iii)-Catalyzed, concise synthesis of marine furanospongian diterpenes†

Antonio Rosales,*ab   Juan Muñoz-Bascón,a   Víctor Manuel Morales-Alcázar,a   José A. Castilla-Alcaláb  and  J. Enrique Oltra*a  

* Corresponding authors

a Department of Organic Chemistry, Faculty of Sciences, University of Granada, Granada, Spain
E-mail: joltra@ugr.es
Fax: +34 958248437

b Department of Clinic Analysis, University Hospital Virgen de las Nieves, Granada, Spain
E-mail: a.rosales.martinez@gmail.com

Abstract

A bioinspired procedure for the straightforward synthesis of marine furanospongian diterpenes is described. The key step is the titanocene(III)-catalyzed radical cascade cyclization of the suitable epoxy-polyprene.

Graphical abstract: Ti(iii)-Catalyzed, concise synthesis of marine furanospongian diterpenes

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Article information

DOI
https://doi.org/10.1039/C2RA22281G
Article type
Paper
Submitted
25 Sep 2012
Accepted
25 Oct 2012
First published
26 Oct 2012

RSC Adv., 2012,2, 12922-12925

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Ti(III)-Catalyzed, concise synthesis of marine furanospongian diterpenes

A. Rosales, J. Muñoz-Bascón, V. Manuel Morales-Alcázar, J. A. Castilla-Alcalá and J. Enrique Oltra, RSC Adv., 2012, 2, 12922 DOI: 10.1039/C2RA22281G

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