Issue 11, 2012
From the journal:

Chemical Science

Rhenium complexes of peripherally π-extended N-confused porphyrins†

Takaaki Yamamoto,a   Motoki Toganoh,a   Shigeki Mori,b   Hidemitsu Unobc  and  Hiroyuki Furuta*ad  

* Corresponding authors

a Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
E-mail: hfuruta@cstf.kyushu-u.ac.jp
Fax: +81 92-802-2865
Tel: +81 92-802-2865

b Department of Molecular Science Integrated Center for Sciences, Ehime University, Bunkyo-cho 2-5, Matsuyama 790-8577, Japan

c Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University, Bunkyo-cho 2-5, Matsuyama 790-8577, Japan

d International Research Center for Molecular Systems, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

Peripherally π-extended N-confused porphyrin rhenium complexes were synthesized by the rhenium-mediated reactions of N-confused porphyrins with 2-methyl azaarene and the structures were elucidated by X-ray crystallographic analyses. Extension of the π-conjugation in the complexes was supported by the absorption spectra, electrochemical measurements and theoretical calculations.

Graphical abstract: Rhenium complexes of peripherally π-extended N-confused porphyrins

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Article information

DOI
https://doi.org/10.1039/C2SC20708G
Article type
Edge Article
Submitted
03 Jun 2012
Accepted
07 Aug 2012
First published
09 Aug 2012

Chem. Sci., 2012,3, 3241-3248

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Rhenium complexes of peripherally π-extended N-confused porphyrins

T. Yamamoto, M. Toganoh, S. Mori, H. Uno and H. Furuta, Chem. Sci., 2012, 3, 3241 DOI: 10.1039/C2SC20708G

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