Issue 6, 2013

Titanium hydrazide gels for Kubas-type hydrogen storage

Abstract

Titanium(III) hydrazide gels designed for Kubas-type hydrogen storage were synthesized from the reaction between tris(bis(trimethylsilyl)methyl) titanium and anhydrous hydrazine. The materials demonstrate a fully reversible H2 adsorption capacity of 2.63 wt% and 36.7 kg m−3 at 298 K and 143 bar without saturation. Interaction between the adsorption center and H2 gas was probed by electron paramagnetic resonance.

Graphical abstract: Titanium hydrazide gels for Kubas-type hydrogen storage

Supplementary files

Article information

Article type
Communication
Submitted
22 Oct 2012
Accepted
13 Dec 2012
First published
13 Dec 2012

J. Mater. Chem. A, 2013,1, 1947-1951

Titanium hydrazide gels for Kubas-type hydrogen storage

T. K. A. Hoang, L. Morris, J. Sun, M. L. Trudeau and D. M. Antonelli, J. Mater. Chem. A, 2013, 1, 1947 DOI: 10.1039/C2TA00795A

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