Issue 8, 2013
From the journal:

Journal of Materials Chemistry A

4-Chloro-3,5-dinitropyrazole: a precursor for promising insensitive energetic compounds†

Chunlin He,a   Jiaheng Zhang,a   Damon A. Parrishb  and  Jean'ne M. Shreeve*a  

* Corresponding authors

a Department of Chemistry, University of Idaho, Moscow, ID 83844-2343, USA
E-mail: jshreeve@uidhao.edu
Fax: +1 208-885-9146

b Naval Research Laboratory, Code 6030, Washington, D.C. 20375-5001, USA

Abstract

A series of 3,5-dinitropyrazole derivatives was prepared from 4-chloro-3,5-dinitropyrazole in good yields and characterized by IR, 1H, and 13C NMR (some cases 15N NMR) spectroscopy, elemental analysis, and DSC. The structures of 7 and 13 were confirmed by single crystal X-ray diffraction. The impact sensitivity was determined using a standard BAM method, and detonation properties were obtained using experimental densities and calculated heats of formation.

Graphical abstract: 4-Chloro-3,5-dinitropyrazole: a precursor for promising insensitive energetic compounds

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2TA01359B
Article type
Paper
Submitted
04 Dec 2012
Accepted
07 Jan 2013
First published
08 Jan 2013

J. Mater. Chem. A, 2013,1, 2863-2868

Permissions

Request permissions

4-Chloro-3,5-dinitropyrazole: a precursor for promising insensitive energetic compounds

C. He, J. Zhang, D. A. Parrish and J. M. Shreeve, J. Mater. Chem. A, 2013, 1, 2863 DOI: 10.1039/C2TA01359B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements