Issue 20, 1972

Crystal and molecular structure of iodo[1,1,1-tris(diphenylphosphinomethyl)ethane]nickel(I)

Abstract

The co-ordination polyhedron in the Ni[MeC(CH2PPh2)3]I complex is a distorted tetrahedron with a P3I donor set; this is the first recorded X-ray structure of a complex of nickel in an unambiguously monovalent state.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 1161-1161

Crystal and molecular structure of iodo[1,1,1-tris(diphenylphosphinomethyl)ethane]nickel(I)

P. Dapporto, G. Fallani, S. Midollini and L. Sacconi, J. Chem. Soc., Chem. Commun., 1972, 1161 DOI: 10.1039/C39720001161

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