Issue 23, 1972
From the journal:

Journal of the Chemical Society, Chemical Communications

Structure of bromobis(triphenylphosphine)-(1,2,3,4-tetrakismethoxycarbonylbuta-1,3-dienyl)palladium and evidence for a C–H ⋯ Pd interaction

D. M. Roe,   P. M. Bailey,   K. Moseley  and  P. M. Maitlis  

Abstract

Treatment of [PdL2{C4(CO2Me)4}] with HX gives trans-PdL2{C4(CO2Me)4H}X; the crystal structure of trans-Pd(Ph3P)2{C4(CO2Me)4}Br is reported and it is shown that there is an interaction between the δ-butadienyl hydrogen and the metal.

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Article information

DOI
https://doi.org/10.1039/C39720001273
Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 1273-1274

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Structure of bromobis(triphenylphosphine)-(1,2,3,4-tetrakismethoxycarbonylbuta-1,3-dienyl)palladium and evidence for a C–H ⋯ Pd interaction

D. M. Roe, P. M. Bailey, K. Moseley and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1972, 1273 DOI: 10.1039/C39720001273

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