Highly functionalised branched-chain monosaccharides can be prepared by sensitised irradiation of conjugated enones (1) and (2) in an alcohol whereupon equatorial 1,4-addition of the carbinol is the major event, the adducts so obtained being correlated with the products of ground-state additions.
B. Fraser-Reid, N. L. Holder and M. B. Yunker, J. Chem. Soc., Chem. Commun., 1972, 1286 DOI: 10.1039/C39720001286
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