Single-crystal X-ray studies have shown the trishexamethyldisilylamides of scandium(III) and europium(III) to have unusual pyramidal three-co-ordinate structures.
J. S. Ghotra, M. B. Hursthouse and A. J. Welch, J. Chem. Soc., Chem. Commun., 1973, 669 DOI: 10.1039/C39730000669
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