Issue 21, 1973

Tris[bis(trimethylsilyl)methyl]tin(III), R3Sn·: an unusually stable stannyl radical, from photolysis of R2Sn

Abstract

Photolysis of R2Sn [R =(Me3Si)2CH] with visible light in benzene at ambient temperature yields the stable radical R3Sn·, which has an e.s.r. solution spectrum showing coupling with the methine protons and 119Sn and 117Sn nuclei.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 829-830

Tris[bis(trimethylsilyl)methyl]tin(III), R3Sn·: an unusually stable stannyl radical, from photolysis of R2Sn

P. J. Davidson, A. Hudson, M. F. Lappert and P. W. Lednor, J. Chem. Soc., Chem. Commun., 1973, 829 DOI: 10.1039/C39730000829

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