Issue 19, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Pentalene complexes from cyclo-octatrienes: crystal structure of η-(1,5-bistrimethylsilyl)pentalene-1,1,2,2,3,3,3,3-octacarbonyl-triangulo-triruthenium, {Ru3(CO)8[C8H4(SiMe3)2]}

Judith A. K. Howard,   Selby A. R. Knox,   F. Gordon A. Stone,   Anne C. Szary  and  Peter Woodward  

Abstract

The trimethylsilyl-substituted cyclo-octa-1,3,6-trienes C8H8(SiMe3)2 and C8H7(SiMe3)3 react with Ru3(O)12 to give the pentalene complexes Ru3(CO)8[C8H4(SiMe3)2] and Ru3(CO)8[C8H3(SiMe3)3], respectively; the molecular structure of the former has been established by an X-ray diffraction study.

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Article information

DOI
https://doi.org/10.1039/C39740000788
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 788-789

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Pentalene complexes from cyclo-octatrienes: crystal structure of η-(1,5-bistrimethylsilyl)pentalene-1,1,2,2,3,3,3,3-octacarbonyl-triangulo-triruthenium, {Ru3(CO)8[C8H4(SiMe3)2]}

J. A. K. Howard, S. A. R. Knox, F. G. A. Stone, A. C. Szary and P. Woodward, J. Chem. Soc., Chem. Commun., 1974, 788 DOI: 10.1039/C39740000788

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