Issue 19, 1974

Unusual emission behaviour of some chromium(III) complexes

Abstract

Two phosphorescence bands in room temperature emission in aqueous solutions of Cr(phen)33+ and Cr(bipy)33+ are assigned origins from 2E and 2T states, the second being a “delayed phosphorescence”; a novel broad band emission from Cr(bipy)33+ in Me2SO is assigned as the first example of quartet fluorescence of a CrIII complex in solution.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 801-802

Unusual emission behaviour of some chromium(III) complexes

N. A. P. Kane-Maguire, J. Conway and C. H. Langford, J. Chem. Soc., Chem. Commun., 1974, 801 DOI: 10.1039/C39740000801

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