Ligand exchange reactions of bis(cyclo-octa-1,5-diene)platinum; synthesis of trisethyleneplatinum and molecular structure of tris-µ-(t-butyl isocyanide)-tris-(t-butyl isocyanide)-triangulo-triplatinum, [Pt3(ButNC)6]

Michael Green; Judith A. Howard; John L. Spencer; F. Gordon A. Stone

doi:10.1039/C39750000003

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Ligand exchange reactions of bis(cyclo-octa-1,5-diene)platinum; synthesis of trisethyleneplatinum and molecular structure of tris-µ-(t-butyl isocyanide)-tris-(t-butyl isocyanide)-triangulo-triplatinum, [Pt₃(Bu^tNC)₆]

Michael Green, Judith A. Howard, John L. Spencer and F. Gordon A. Stone

Abstract

The reaction of [Pt(1,5-C₈H₁₂)₂] with Bu^tNC yields [Pt₃(Bu^tNC)₆], structurally identified by X-ray crystallography, and with tricyclohexylphosphine and ethylene affords [Pt(PCy₃)₂] and [Pt(C₂H₄)₃] respectively (Cy = cyclohexyl); the 14-electron phosphine complex reacts with hydrogen to give trans-[PtH₂(PCy₃)₂].

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DOI: https://doi.org/10.1039/C39750000003
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1975, 3-4

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Ligand exchange reactions of bis(cyclo-octa-1,5-diene)platinum; synthesis of trisethyleneplatinum and molecular structure of tris-µ-(t-butyl isocyanide)-tris-(t-butyl isocyanide)-triangulo-triplatinum, [Pt₃(Bu^tNC)₆]

M. Green, J. A. Howard, J. L. Spencer and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1975, 3 DOI: 10.1039/C39750000003

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Journal of the Chemical Society, Chemical Communications

Ligand exchange reactions of bis(cyclo-octa-1,5-diene)platinum; synthesis of trisethyleneplatinum and molecular structure of tris-µ-(t-butyl isocyanide)-tris-(t-butyl isocyanide)-triangulo-triplatinum, [Pt₃(Bu^tNC)₆]

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Ligand exchange reactions of bis(cyclo-octa-1,5-diene)platinum; synthesis of trisethyleneplatinum and molecular structure of tris-µ-(t-butyl isocyanide)-tris-(t-butyl isocyanide)-triangulo-triplatinum, [Pt₃(Bu^tNC)₆]

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